Daphniphylline
IUPAC 名称
(2S)-1-[(1R,4R,5S)-1,4-dimethyl-2,8-dioxabicyclo[3.2.1]octan-4-yl]-3-[(3S,7R,10S,13S,14R)-1-methyl-14-(propan-2-yl)-12-azapentacyclo[8.6.0.0^{2,13}.0^{3,7}.0^{7,12}]hexadecan-2-yl]-1-oxopropan-2-yl acetate
描述
Isolated from the bract of Hibiscus sabdariffa (roselle) [DFC]
One of the main alkaloids from Daphniphyllum macropodum and Daphniphyllum teijsmanniand is also isolated from the bark of Daphniphyllum gracile and from the dried calyx and bract of Hibiscus sabdariffa (Daphniphyllaceae, Malvaceae) [CCD]. Daphniphylline is found in herbs and spices.
异构
[H][C@@]12CCC[C@@]11CC[C@@H]3CN1[C@H]1[C@H](CCC3(C)C21C[C@H](OC(C)=O)C(=O)[C@]1(C)CO[C@@]2(C)CC[C@@H]1O2)C(C)C
InChI标识符
InChI=1S/C32H49NO5/c1-19(2)22-10-13-29(5)21-9-15-31-12-7-8-24(31)32(29,26(22)33(31)17-21)16-23(37-20(3)34)27(35)28(4)18-36-30(6)14-11-25(28)38-30/h19,21-26H,7-18H2,1-6H3/t21-,22-,23+,24-,25+,26+,28-,29?,30-,31-,32?/m1/s1
键
LFLWRPZTBUUBEQ-NIECOALOSA-N